Date of Award
Fall 2023
Access Type
Thesis - Open Access
Degree Name
Master of Science in Aerospace Engineering
Department
Aerospace Engineering
Committee Chair
Sirish Namilae
First Committee Member
Mandar Kulkarni
Second Committee Member
Alberto Mello
College Dean
James Gregory
Abstract
The carbon fiber/epoxy interface is of great importance in composite design due to its load transfer mechanisms from the weak epoxy to the stronger fiber. Improving the strength of the interface reduces the risk of failure at the interface and improves the load transfer to the fiber. In this study, two types of nano-species ZnO nanowires and nickel-based metal organic frameworks were grown on carbon fibers to improve the interfaces. The interfacial mechanics of the enhanced fibers are evaluated using nanoindentation studies. Composite samples with Aeropoxy matrix and vertically aligned fibers are fabricated for this purpose. A Bruker TI-980 TriboIndenter is used to perform single-fiber push-in tests to analyze the interfacial behavior. The load-displacement curves of these push-in tests denote a clear nonlinearity where debonding occurs, and the debonding loads are used to calculate interfacial shear stress. A 15-20% improvement in interfacial strength was observed with the fiber modification. Along with that, modulus mapping techniques allow for the analysis of the change in moduli along the interface. In conjunction with mechanical analysis, chemical and hydrodynamic perspectives are also investigated for additional reasoning as to why nano-species surface modification positively affects the fiber/matrix interface. These perspectives show that the increase in roughness on the fiber’s surface, increase in surface free energy, and decrease in interfacial tension of the nano-species increases the wettability of the epoxy onto the fiber’s surface. The combined mechanical, chemical, and hydrodynamic analyses lead to the conclusion that the growth of these nano-species enhances the interfacial properties of the carbon fibers and opens promising possibilities for multifunctional applications by harnessing the properties of the nanomaterials.
Scholarly Commons Citation
Srihari, Sriraj, "Interfacial Thermomechanical Behavior of Hybrid Carbon Fibers" (2023). Doctoral Dissertations and Master's Theses. 769.
https://commons.erau.edu/edt/769
Included in
Nanoscience and Nanotechnology Commons, Polymer and Organic Materials Commons, Structures and Materials Commons